Experimental studies of Debye-like process and structural relaxation in mixtures of 2-ethyl-1-hexanol and 2-ethyl-1-hexyl bromide

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Experimental studies of Debye-like process and structural relaxation in mixtures of 2-ethyl-1-hexanol and 2-ethyl-1-hexyl bromide.

Binary solutions of 2-ethyl-1-hexanol (2E1H) with 2-ethyl-1-hexyl bromide (2E1Br) are investigated by means of dielectric, shear mechanical, near-infrared, and solvation spectroscopy as well as dielectrically monitored physical aging. For moderately diluted 2E1H the slow Debye-like process, which dominates the dielectric spectra of the neat monohydroxy alcohol, separates significantly from the ...

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Experimental results of dielectric investigations for binary mixtures of 2, 3-butanediol, 2, 3-BD, in2-ethyl-1-hexanol, 2EH, were reported for various mole fractions and temperatures (298.2-308.2) Kand they were used to calculate dielectric parameters such as Kirkwood correlation factor, excesspermittivity and Bruggeman parameter. These parameters were used to carry out temperaturedependent die...

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dielectric and thermodynamic properties of 2, 3-butanediol + 2-ethyl-1-hexanol mixtures

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Dielectric relaxation of 2-ethyl-1-hexanol around the glass transition by thermally stimulated depolarization currents.

We explore new routes for characterizing the Debye-like and α relaxation in 2-ethyl-1-hexanol (2E1H) monoalcohol by using low frequency dielectric techniques including thermally stimulated depolarization current (TSDC) techniques and isothermal depolarization current methods. In this way, we have improved the resolution of the overlapped processes making it possible the analysis of the data in ...

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ژورنال

عنوان ژورنال: The Journal of Chemical Physics

سال: 2012

ISSN: 0021-9606,1089-7690

DOI: 10.1063/1.4755754